1,3,5-三苯基苯
化合物
1,3,5-三苯基苯是一种有机化合物，化学式为C24H18。它可由苯乙炔的环聚合反应得到：[2]
| 1,3,5-三苯基苯 | |
|---|---|
| |
| |
| 识别 | |
| CAS号 | 612-71-5 
|
| PubChem | 11930 |
| 性质 | |
| 化学式 | C24H18 |
| 摩尔质量 | 306.4 g·mol−1 |
| 熔点 | 176 °C（449 K）[1] |
| 沸点 | 462 °C（735 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
该反应同时会产生1,2,4-三苯基苯。苯硼酸和1,3,5-三溴苯在钯催化下发生铃木偶联反应，也能制得1,3,5-三苯基苯。[3]它可以和乙酰氯在三氯化铝催化下于二硫化碳中反应，得到1,3,5-三(4-乙酰苯基)苯。[4]它和溴反应得到2-溴-1,3,5-三苯基苯[5]；它的氢化反应可以得到1,3,5-三环己基环己烷。[6]
参考文献
编辑- ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2021-06-25].
- ^ Nicolas Agenet, Olivier Buisine, Franck Slowinski, Vincent Gandon, Corinne Aubert, Max Malacria. John Wiley & Sons, Inc. , 编. Cotrimerizations of Acetylenic Compounds. Hoboken, NJ, USA: John Wiley & Sons, Inc. 2007-03-12: 1–302 [2021-06-25]. ISBN 9780471264187. doi:10.1002/0471264180.or068.01 （英语）.
- ^ Yunlong Sun, Tian Li. Fabrication and Application of Graphene Supported Diimine‐Palladium Complex Catalyst for Organic Synthesis. ChemistrySelect. 2020-01-31, 5 (4): 1431–1438 [2021-06-25]. ISSN 2365-6549. doi:10.1002/slct.201904488 （英语）.
- ^ Yannick Matt, Isabelle Wessely, Lisa Gramespacher, Manuel Tsotsalas, Stefan Bräse. Rigid Multidimensional Alkoxyamines: A Versatile Building Block Library. European Journal of Organic Chemistry. 2021-01-15, 2021 (2): 239–245 [2021-06-25]. ISSN 1434-193X. doi:10.1002/ejoc.202001415 （英语）.
- ^ Roderick C. Jones, Allan J. Canty, Tom Caradoc-Davies, Noel W. Davies, Michael G. Gardiner, Philip J. Marriott, Christian P. G. Rühle, Vicki-Anne Tolhurst. A new mechanistic pathway under Sonogashira reaction protocol involving multiple acetylene insertions. Dalton Transactions. 2010, 39 (16): 3799 [2021-06-25]. ISSN 1477-9226. doi:10.1039/c001109f （英语）.
- ^ Raed Abu-Reziq, David Avnir, Irena Miloslavski, Herbert Schumann, Jochanan Blum. Entrapment of metallic palladium and a rhodium(I) complex in a silica sol–gel matrix. Journal of Molecular Catalysis A: Chemical. 2002-07, 185 (1-2): 179–185 [2021-06-25]. doi:10.1016/S1381-1169(02)00012-2. （原始内容存档于2018-06-24） （英语）.