4-氯异丙苯
化合物
4-氯异丙苯是一种有机氯化合物,化学式为C9H11Cl。它可由异丙苯和氯气在乙酸中,或和次氯酸叔丁酯在沸石存在下于乙腈中反应制得,该反应会产生少量的2-氯异丙苯。[2]在氯化亚铁催化下,它可以被过氧化氢氧化为4'-氯苯乙酮。[3]
4-氯异丙苯 | |
---|---|
![]() | |
识别 | |
CAS号 | 2621-46-7 ![]() |
SMILES |
|
性质 | |
化学式 | C9H11Cl |
摩尔质量 | 154.64 g·mol−1 |
熔点 | −12.3 °C[1] |
沸点 | 198.3 °C[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
编辑- ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2024-07-02].
- ^ Smith, Keith; Butters, Michael; Nay, Barry. Highly para-Selective Mono-Chlorination of Aromatic Compounds Under Mild Conditions by t-Butyl Hypochlorite in the Presence of Zeolites. Synthesis, 1985 (12), 1157–1158. doi:10.1055/s-1985-31462
- ^ Ning Xu, Lulu Zhou, Linlin Zhao, Mengying Guo, Linlin Yang, Wei Han. Iron-Catalyzed Oxidative C−C Bond Cleavage of Unstrained Tertiary Alkyl Aromatics to Arylketones. Advanced Synthesis & Catalysis. 2023. 365 (15). doi:10.1002/adsc.202300410.