4-氯叔丁苯

化合物

4-氯叔丁苯是一种有机氯化合物,化学式为C10H13Cl。它可由氯苯2-甲基-2-丁烯氯化铝催化下反应得到。[2]

4-氯叔丁苯
识别
CAS号 3972-56-3  checkY
SMILES
 
  • ClC1=CC=C(C=C1)C(C)(C)C
性质
化学式 C10H13Cl
摩尔质量 168.66 g·mol−1
熔点 22.5 °C[1]
沸点 210-212 °C[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

叔丁醇钾的存在下和钯配合物的催化下,它可以发生脱氯反应,得到叔丁苯[3]它和硝酸硫酸反应,可以得到4-叔丁基-2-硝基氯苯。[4]

参考文献

编辑
  1. ^ Leon M. Stock and Herbert C. Brown. Relative Rates and Isomer Distributions in the Halogenation of t-Butylbenzene and Some of Its Derivatives. Partial Rate Factors for Non-catalytic Bromination and Chlorination in Acetic Acid. J. Am. Chem. Soc. 1959. 81 (21). doi:10.1021/ja01530a024
  2. ^ 2.0 2.1 B. S. Friedman and Fred L. Morritz. t-Butylation of Aromatics with Isoamylene. J. Am. Chem. Soc. 1956. 78 (14). doi:10.1021/ja01595a046.
  3. ^ Angela Burhenn, Roberta Bavaro and Viktoria H. Gessner. Pd-catalysed hydrodehalogenation of aryl chlorides: a mild method for deuteration and detoxification. Catal. Sci. Technol., 2023,13, 3545-3550. doi:10.1039/D3CY00432E.
  4. ^ Yvonne Grell, Nemrud Demirel, Klaus Harms, and Eric Meggers. Chiral Bis(oxazoline) Ligands as C2-Symmetric Chiral Auxiliaries for the Synthesis of Enantiomerically Pure Bis-Cyclometalated Rhodium(III) Complexes. Organometallics 2019, 38, 19, 3852–3859. doi:10.1021/acs.organomet.9b00533.