奥林匹克烷

化合物

奥林匹克烷(Olympiadane)是一种機械互鎖結構分子,由五个类似奥运五环的互锁大环组成。分子是线性五联环烃或五聯索烃。它由Fraser Stoddart英语Fraser Stoddart及其同事于1994年合成并命名[1]。该分子出于对有机合成的可能性探索[2],并未考虑任何实际用途。类似的链环烃可能会用于分子计算机的构建。

奥林匹克烷
Skeletal formula of olympiadane
Ball-and-stick models of the component ions of olympiadane
IUPAC名
6,9,12,15,18,29,32,35,38,41,52,55,58,61,64-pentadecaoxaheptacyclo[63.4.0.05,69.019,24.023,28.042,47.046,51]nonahexaconta-1(69),2,4,19,21,23,25,27,42,44,46,48,50,65,67-pentadecaene;5,12,19,26-tetrazoniaheptacyclo[24.2.2.22,5.27,10.212,15.216,19.221,24]tetraconta-1(29),2(40),3,5(39),7,9,12,14,16(34),17,19(33),21(32),22,24(31),26(30),27,35,37-octadecaene;dodecahexafluorophosphate
识别
CAS号 158394-29-7  checkY
PubChem 71308249
ChemSpider 26000999
SMILES
 
  • c1cc2c3cccc2OCCOCCOCCOCCOc4cccc5c4cccc5OCCOCCOCCOCCOc6cccc7c6cccc7OCCOCCOCCOCCOc3c1.c1cc2c3cccc2OCCOCCOCCOCCOc4cccc5c4cccc5OCCOCCOCCOCCOc6cccc7c6cccc7OCCOCCOCCOCCOc3c1.c1cc2ccc1C[n+]3ccc(cc3)-c4cc[n+](cc4)Cc5ccc(cc5)C[n+]6ccc(cc6)-c7cc[n+](cc7)C2.c1cc2ccc1C[n+]3ccc(cc3)-c4cc[n+](cc4)Cc5ccc(cc5)C[n+]6ccc(cc6)-c7cc[n+](cc7)C2.c1cc2ccc1C[n+]3ccc(cc3)-c4cc[n+](cc4)Cc5ccc(cc5)C[n+]6ccc(cc6)-c7cc[n+](cc7)C2.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F
性质
化学式 C228H236F72N12O30P12
摩尔质量 5363.95 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

另见

编辑

參考資料

编辑
  1. ^ Amabilino, D. B.; Ashton, P. R.; Reder, A. S.; Spencer, N.; Stoddart, J. F. Olympiadane. Angew. Chem. Int. Ed. Engl. 1994, 33 (12): 1286–1290. doi:10.1002/anie.199412861. 
  2. ^ Browne, M. W. Chemists Make Rings Of Interlocked Atoms, A Clue to Life's Origin. The New York Times. 30 August 1994 [3 January 2016]. (原始内容存档于2021-07-11).