四氟化钌

四氟化钌
别名	Ruthenium tetrafluoride
识别
CAS号	71500-16-8
PubChem	167109
ChemSpider	146211
SMILES	[F-].[F-].[F-].[F-].[Ru+4];
EINECS	238-533-8
性质
化学式	F4Ru
摩尔质量	177.07 g·mol−1
外观	粉色晶体
溶解性（水）	反应
结构
晶体结构	单斜
相关物质
相关化学品	四氟化铑, 四氟化铂
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

四氟化钌是一种无机化合物，化学式为RuF
4。^[1]^[2]它最初在1963年由Holloway和Peacock用碘在五氟化碘中还原五氟化钌制得。^[3]

10RuF
5 + I
2 → 10RuF
4 + 2IF
5

后来的研究证明通过这种方式得到的RuF
4不纯，纯净的样品最早在1992年由KRuF
6和AsF
5在20 °C无水氟化氢中反应制得。^[4]^[5]

K
2RuF
6 + 2AsF
5 → RuF
4 + 2KAsF
6

参考文献

^ Casteel, William J.; Wilkinson, Angus P.; Borrmann, Horst; Serfass, Robert E.; Bartlett, Neil. Preparation and structure of ruthenium tetrafluoride and a structural comparison with ruthenium trifluoride and ruthenium pentafluoride. Inorganic Chemistry. July 1992, 31 (14): 3124–3131 [10 April 2023]. ISSN 0020-1669. doi:10.1021/ic00040a024 （英语）.
^ Bartlett, Neil. The Oxidation of Oxygen and Related Chemistry: Selected Papers of Neil Bartlett. World Scientific. 2001: 306 [10 April 2023]. ISBN 978-981-281-198-1 （英语）.
^ Reactor Fuel Processing. U.S. Argonne National Laboratory. 1963: 28 [10 April 2023] （英语）.
^ Casteel, William J.; Wilkinson, Angus P.; Borrmann, Horst; Serfass, Robert E.; Bartlett, Neil. Preparation and structure of ruthenium tetrafluoride and a structural comparison with ruthenium trifluoride and ruthenium pentafluoride. Inorganic Chemistry. July 1992, 31 (14): 3124–3131 [10 April 2023]. ISSN 0020-1669. doi:10.1021/ic00040a024 （英语）.
^ Esteban, G. L.; Kerr, J. A.; Trotman-Dickenson, A. F.; Gronowitz, S.; Katritzky, A. R.; Reavill, R. E.; Ridgewell, B. J.; Green, M.; Hudson, R. F.; Brimacombe, J. S.; How, M. J.; Acheson, R. M.; Miller, G. R.; Plunkett, A. O.; Cavell, R. G.; Clark, H. C.; Holloway, J. H.; Peacock, R. D.; Ebsworth, E. a. V.; Mays, M. J.; Handford, B. O.; Whalley, W. B.; Grundon, M. F.; Reynolds, B. E.; Sayigh, A. a. R.; Ulrich, Henri; Rubinfeld, J.; Palmer, P. J.; Hollingsworth, B. L.; Tuck, D. G.; Bott, R. W.; Eaborn, C.; Hashimoto, T.; Craig, J. Cymerman; Moyle, M.; Tidd, B. K.; Arthur, H. R.; Ollis, W. D.; Greenwood, N. N.; Wallbridge, M. G. H.; Bentley, K. W.; Dyke, S. F.; Marshall, A. R.; Smith, E. E.; Whelan, W. J.; Finan, P. A.; Ahmed, M. T.; Swallow, A. J. Notes. Journal of the Chemical Society (Resumed). 1 January 1963: 3879–3919 [10 April 2023]. ISSN 0368-1769. doi:10.1039/JR9630003879 （英语）.

[1] Casteel, William J.; Wilkinson, Angus P.; Borrmann, Horst; Serfass, Robert E.; Bartlett, Neil. Preparation and structure of ruthenium tetrafluoride and a structural comparison with ruthenium trifluoride and ruthenium pentafluoride. Inorganic Chemistry. July 1992, 31 (14): 3124–3131 [10 April 2023]. ISSN 0020-1669. doi:10.1021/ic00040a024 （英语）.

[2] Bartlett, Neil. The Oxidation of Oxygen and Related Chemistry: Selected Papers of Neil Bartlett. World Scientific. 2001: 306 [10 April 2023]. ISBN 978-981-281-198-1 （英语）.

[3] Reactor Fuel Processing. U.S. Argonne National Laboratory. 1963: 28 [10 April 2023] （英语）.

[4] Casteel, William J.; Wilkinson, Angus P.; Borrmann, Horst; Serfass, Robert E.; Bartlett, Neil. Preparation and structure of ruthenium tetrafluoride and a structural comparison with ruthenium trifluoride and ruthenium pentafluoride. Inorganic Chemistry. July 1992, 31 (14): 3124–3131 [10 April 2023]. ISSN 0020-1669. doi:10.1021/ic00040a024 （英语）.

[5] Esteban, G. L.; Kerr, J. A.; Trotman-Dickenson, A. F.; Gronowitz, S.; Katritzky, A. R.; Reavill, R. E.; Ridgewell, B. J.; Green, M.; Hudson, R. F.; Brimacombe, J. S.; How, M. J.; Acheson, R. M.; Miller, G. R.; Plunkett, A. O.; Cavell, R. G.; Clark, H. C.; Holloway, J. H.; Peacock, R. D.; Ebsworth, E. a. V.; Mays, M. J.; Handford, B. O.; Whalley, W. B.; Grundon, M. F.; Reynolds, B. E.; Sayigh, A. a. R.; Ulrich, Henri; Rubinfeld, J.; Palmer, P. J.; Hollingsworth, B. L.; Tuck, D. G.; Bott, R. W.; Eaborn, C.; Hashimoto, T.; Craig, J. Cymerman; Moyle, M.; Tidd, B. K.; Arthur, H. R.; Ollis, W. D.; Greenwood, N. N.; Wallbridge, M. G. H.; Bentley, K. W.; Dyke, S. F.; Marshall, A. R.; Smith, E. E.; Whelan, W. J.; Finan, P. A.; Ahmed, M. T.; Swallow, A. J. Notes. Journal of the Chemical Society (Resumed). 1 January 1963: 3879–3919 [10 April 2023]. ISSN 0368-1769. doi:10.1039/JR9630003879 （英语）.

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